Well, maybe one does: a jokey shot taken in 1953 (whose rights he signed away), showing him with a sour, headachey expression of generic woe; it has been used dozens of times, even in the last decade, in ads for aspirin, tax services, hangover remedies and other stress relievers.
Meaning of headachey for the defined word.
Grammatically, this word "headachey" is an adjective.